It may not be necessary to replace the cylinder head; But change the joint between it, and the motor block. Surely the cylinder head will need a rectification, and it is something that I recommend doing shortly, I do not advise you to continue using the vehicle like that, because the damage can be aggravated, to the point of melting the engine.
The same with the cooling system, a vehicle that does not work its electro -ventilator should not be shot, and that the entire cooling circuit does not work perfectly.
Actually, the burned butt joint is nothing more than the result of the high temperatures at which the engine reached for not having its cooling,
therefore, both things would have to be repaired.
I know that things are complicated in Spain, and it is not my intention to complicate you making you repair this urgent, but unfortunately, your vehicle can be seriously damaged to continue rolling in those conditions.
Good luck!